Why is Polycarboxylate Superplasticizer Modified?
Commodity prices are on track for their biggest rally in more than a century, while fixed-income assets have seen their longest run of outflows as the war in Ukraine adds to inflationary pressures in the global economy emerging from the coronavirus lockdown, according to Bank of America.
"Commodity prices this year are on track to record their biggest gains since 1915." the bank said in its weekly briefing. They cite many factors, such as pandemics, lockdown, civil strife, wars, excessive monetary and fiscal stimulus, and supply chain disruptions, that have led to "historically" high inflation.
By the same token, it said government bonds were heading for their worst year since 1949, and "negative-yielding bonds will quietly disappear" from the market as central banks embark on a monetary tightening cycle and raise interest rates to tame soaring inflation.
The prices of many commodities like the concrete superplasticizer are expected to increase in the future.
Concrete water reducing agent is one of the technical ways to reduce the cement dosage, improve the utilization rate of industrial waste residue, and realize the durability and high performance of concrete. It is also one of the key materials for the development of concrete to high-tech field. And polycarboxylate type water reducing agent (PC) has become a kind of efficient water reducing agent with the most rapid development and the largest market potential because of its low toxicity and environmental protection characteristics. Compared with the traditional admixtures, the admixtures have become the focus of worldwide research and development because of their excellent dispersibility and slump retention ability.
Although polycarboxylate water reducing admixture outstanding performance and ability to maintain good slump has been widely recognized, but because of the existence of mineral composition, cement fineness, cement plaster form and content, admixture adding amount, and the mixing process of concrete mixture ratio, water has a very high sensitivity, seriously affected the existing products are widely used in engineering.
What is Polycarboxylate Series Water Reducing Agent?
Polycarboxylate superplasticizer is a kind of surfactant containing carboxylic graft copolymer. Its molecules are comb shaped and have high steric hindrance effect. As the third generation of high-performance water reducing agent after lignosulfonate ordinary water reducing agent, naphthalene series aliphatic group, sulfamate and other high-efficiency water reducing agent.
It is because of molecular structure design performance is good, high reduce water, low admixture amount, keep slump good, enhance good, contain alkali amount is low, to set time influence is small, and most cement compatibility is good and pollution-free and other advantages are regarded as the most development potential of water reducing agent variety.
Polycarboxylate superplasticizer is a new high-efficiency superplasticizer developed and produced successfully after naphthalene, melamine, aliphatic and sulfamate superplasticizer. In its content is low (solid content 0.15% - 0.25%) can produce an ideal water reducing and enhanced effect, less impact on the setting time of concrete and slump retention, adaptability to cement and admixture is relatively good, a smaller influence on drying shrinkage of concrete (usually not too much increase drying shrinkage), without the use of formaldehyde in the process of production and does not discharge waste liquor, SO The low content of 42- and Cl- has been praised by researchers and some users since the beginning.
Why should Polycarboxylate Superplasticizer be Modified?
Compared with naphthalene series high efficient water reducing agent, such as, although poly carboxylic acid water reducing agent in the reduction of water conservation slump has obvious advantages in aspects of environmental protection, but there are some technical problems in the practical engineering application, such as water reducing effect of concrete raw materials, mixing ratio, water reducing agent dosage dependence is very big, fresh concrete performance is sensitive to water consumption, easy preparation of large liquidity segregation layer. Poor compatibility with other water-reducing agents and modified components and poor product stability greatly restrict the wide application and development of polycarboxylate water-reducing agents.
In order to overcome the technical defects in the application of polycarboxylate water-reducing agent, or to improve some or some properties of concrete (workability, slump retention, reduction of bleeding, improvement of early strength, low shrinkage, etc.), it is necessary to modify the concrete.
In practice, the commonly used modification methods include synthetic technology and compound technology. Compared with the synthetic process, the compound method has the advantages of simple operation and low cost, so it is widely used in practical applications. Polycarboxylate series compound technology, is the polycarboxylate series water-reducing agent and other components (such as slow coagulation, defoamy, air induction, early strength and other components) according to a certain proportion of the combination compound, in order to achieve the coordination of the superposition of each component.
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With the outbreak of the Russia-Ukraine conflict, the market is increasingly worried about the potential disruption of Russia's energy supply. Geopolitical premiums have pushed up the price of crude oil and natural gas, and the energy price is expected to remain high in the short term. Affected by this, the market price of the concrete superplasticizer may continue to rise.